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You can install Bazzite and you will have the same experience you would get with SteamOS. Don’t use the extra features and you won’t be able to tell the difference. It is a “just works” experience with minimal setup. The setup even includes emulators and launchers like the FFXIV one so it is even more minimal than SteamOS.
It may not work directly on a given PC or a specific device, but that would also happen if Valve released a generic SteamOS.
Edit: typo
It’s probably not worth the risk implied with second hand vs the discounted new unit directly from Valve. You should lower it or just assume you’re not going to sell it