It would be more likely a secondary or tertiary effect. That is, H• radicals ripped away from their parent molecules would leave •OH, •R, and •RNH radicals. These are unstable and highly reactive, “desiring” to have that stable electron configuration. Likely, this will result in elections being shifted to bring in more stable species, like OH-. Overall, we’re looking at effectively a deprotonation of the saliva, with extra intermediary steps to stabilize the radicals.
Interesting. Given that H• is a neutral species, what would cause the preference for the creation of stable negative species (freeing up H+) over the creation of stable positive species (freeing up OH-)?
It would be more likely a secondary or tertiary effect. That is, H• radicals ripped away from their parent molecules would leave •OH, •R, and •RNH radicals. These are unstable and highly reactive, “desiring” to have that stable electron configuration. Likely, this will result in elections being shifted to bring in more stable species, like OH-. Overall, we’re looking at effectively a deprotonation of the saliva, with extra intermediary steps to stabilize the radicals.
Interesting. Given that H• is a neutral species, what would cause the preference for the creation of stable negative species (freeing up H+) over the creation of stable positive species (freeing up OH-)?